Scarlett first won the sexiest woman alive title back in 2006 and she is the first woman to win the title twice.
The Esquire list of the sexiest woman alive always sparks up plenty of discussion about who should be on the list and isn’t and who is on the list and shouldn’t be!
Previous winners of the title include Angelina Jolie, Minka Kelly, Jessica Biel, Halle Berry, Rihanna, Kate Beckinsale, Charlize Theron and Mila Kunis, who took the title last year.
As is traditional for winners of the sexiest woman award Scarlett is also the cover girl of the special edition of Esquire magazine. Well who else could you get to go on the cover.
Here are some of the photos from the special Esquire sexiest woman alive photoshoot for you to enjoy.